Infrared technology
over time
Less than 200 years ago the existence of the infrared portion of the
electromagnetic spectrum wasn't even suspected.
The original significance of the infrared spectrum,
or simply 'the infrared' as it is often called,
as a form of heat radiation is perhaps less obvious today than it was at the time of its discovery by Herschel
in 1800.
Sir
William Herschel (1738-1822)
The discovery was made accidentally during
the search for a new optical material. Sir William Herschel - Royal Astronomer to King
George III of England, and already famous for his discovery of the planet Uranus - was searching for an optical
filter material to reduce the brightness of
the sun's image in telescopes during solar
observations. While testing different samples
of colored glass which gave similar reductions
in brightness he was intrigued to find that
some of the samples passed very little of the sun's heat, while others passed so much heat that he risked eye damage
after only a few seconds' observation.
Herschel was soon convinced of the necessity of setting up a systematic
experiment, with the objective of finding a
single material that would give the desired
reduction in brightness as well as the maximum
reduction in heat. He began the experiment
by actually repeating Newton's prism experiment,
but looking for the heating effect rather than the visual distribution of intensity in the spectrum. He first
blackened the bulb of a sensitive mercury-in-gfass
thermometer with ink, and with this as his
radiation detector
he proceeded to test the heating effect of
the various colors of the spectrum formed
on the top of a table by passing sunlight through
a glass prism. Other thermometers, placed outside the sun's rays, served
as controls.
As the blackened thermometer was moved slowly along the colors of
the spectrum, the temperature readings showed
a steady increase from the violet end to the
red end. This was not entirely unexpected,
since the Italian researcher, Landriani, in
a similar experiment in 1777 had observed much
the same effect. It was Herschel, however,
who was the first to recognize that there must
be a point where the heating
effect
reaches a maximum, and that measurements confined
to the visible portion of the spectrum failed
to locate this point.
Marsillio
Landriani (1746-1815)
Moving the thermometer into the dark region beyond the red end of
the spectrum, Herschel confirmed that the heating
continued to increase. The maximum point, when
he found it, lay well beyond the red end -
in what is known today as the 'infrared wavelengths'.
When Herschel revealed his discovery,
he referred to this new portion of the electromagnetic spectrum as the 'thermometrical
spectrum'. The radiation itself he sometimes referred to as 'dark heat', or simply 'the
invisible rays'. Ironically, and contrary to popular
opinion, it wasn't Herschel who originated
the term 'infrared'. The word only began to
appear in print around 75 years later, and
it is still unclear who should receive credit
as the originator.
Herschel's use of glass in the prism of his original experiment
led to some early controversies with his
contemporaries about the actual existence of
the infrared wavelengths.
Different investigators, in attempting to confirm
his work, used various types of glass indiscriminately,
having different transparencies in the infrared.
Through his later experiments, Herschel
was aware of the limited transparency of glass
to the newly-discovered thermal radiation,
and he was forced to conclude that optics for
the infrared would probably be doomed to the
use of reflective elements exclusively (i.e.
plane and curved mirrors). Fortunately, this
proved to be true only until 1830, when the Italian investigator, Melloni, made his great discovery that
naturally occurring rock salt (NaCI)
- which was available in large enough natural
crystals to be made into lenses
and prisms - is remarkably transparent to the
infrared. The result was that rock salt
became the principal infrared optical material,
and remained so for the next hundred years,
until the art of synthetic crystal growing
was mastered in the 1930's.
Macedonio Melloni (1798-1854)
Thermometers, as radiation detectors, remained unchallenged until
1829, the year Nobili invented the thermocouple.
(Herschel's own thermometer could be read to
0.2 °C
(0.036 °F), and later
models were able to be read to 0.05 °C (0.09 °F)). Then a breakthrough occurred; Melloni
connected a number of thermocouples in series
to form the first thermopile. The new device
was at least 40 times as sensitive as the best
thermometer of the day for detecting heat radiation -capable of
detecting the heat from a person standing three
meters away.
The first so-called 'heat-picture' became possible in 1840, the
result of work by Sir John Herschel, son of
the discoverer of the infrared and a famous
astronomer in his own right. Based upon the
differential evaporation of a thin film of
oil when exposed to a heat pattern focused
upon it, the thermal image could be seen by
reflected light where the interference effects
of the oil film made the image visible to the
eye. Sir John also managed to obtain a primitive record of the thermal image on
paper, which he
called a 'thermograph'.
Samuel P. Langley (1834-1906)
The improvement of infrared-detector sensitivity progressed slowly.
Another major breakthrough, made by Langley
in 1880, was the invention of the bolometer.
This consisted of a thin blackened strip of platinum connected
in one arm of a Wheatstone bridge circuit upon which the infrared radiation was focused and
to which a sensitive galvanometer responded.
This instrument is said to have been able to
detect the heat
from a cow at a distance of 400 meters.
An English scientist, Sir James Dewar, first introduced the use
of liquefied gases as cooling
agents (such as liquid nitrogen with a temperature
of -196 °C (-320.8 °F)) in low temperature research.
In 1892 he invented a unique vacuum insulating
container in which it is possible
to store liquefied gases for entire days. The
common 'thermos bottle', used for storing hot and cold drinks,
is based upon his invention.
Between the years 1900 and 1920, the
inventors of the world 'discovered' the infrared. Many patents were issued for devices to detect
personnel, artillery, aircraft, ships -and
even icebergs. The first operating systems,
in the modern sense, began to be developed
during the 1914-18 war, when both sides had
research programs devoted to the military exploitation
of the infrared. These programs included experimental systems for enemy intrusion/detection, remote temperature
sensing, secure communications,
and 'flying torpedo' guidance. An infrared
search system tested during this period was able to detect an approaching airplane
at a distance of 1.5 km (0.94 miles), or
a person more than 300 meters (984 ft.) away.
The most sensitive systems up to this time were all based upon variations
of the bolometer idea, but the period between
the two wars saw the development of two revolutionary
new infrared detectors: the image converter
and the photon detector. At
first, the image converter received the greatest
attention by the military, because it enabled an observer for the first time in history
to literally 'see in the dark'. However, the
sensitivity of the image converter was limited
to the near infrared wavelengths, and the most
interesting military targets (i.e. enemy soldiers)
had to be illuminated by infrared search beams.
Since this involved the risk of giving away
the observer's position to a similarly-equipped
enemy observer, it is understandable that military interest
in the image converter eventually faded.
The tactical military disadvantages of so-called 'active' (i.e.
search beam-equipped) thermal imaging systems
provided impetus following the 1939-45 war
for extensive secret
military infrared-research programs into the
possibilities of developing 'passive' (no
search beam) systems around the extremely sensitive
photon detector. During this period, military secrecy regulations completely
prevented disclosure of the status of infrared-imaging technology. This secrecy only began to be lifted
in the middle of the 1950's, and from
that time adequate thermal-imaging devices
finally began to be available to civilian science
and industry.
middle infrared (3-6 |jm), the far
infrared (6-15 um) and the extreme
infrared (15-100 um). Although the wavelengths are given in
|jm (micrometers), other units are often
still used to measure wavelength in this
spectral region, e.g. nanometer (nm)
and Angstrom (A).
The relationships between the different wavelength
measurements is:
10,000 A = 1000nm = 1u =1um
Blackbody radiation
A
blackbody is defined as an object which absorbs
all radiation that impinges on it at any wavelength. The apparent misnomer black relating
to an object emitting radiation
is explained by Kirchhoff's Law (after GustavRobertKirchhoff,
1824-1887),
which states that a body capable of absorbing
all radiation at any wavelength is equally
capable in the emission of radiation.

Gustav Robert Kirchhoff (1824-1887)
The construction of a blackbody source is, in principle, very simple.
The radiation characteristics of an aperture
in an isotherm cavity made of an opaque absorbing material
represents almost exactly the properties of
a blackbody. A practical application of the principle to the construction of a
perfect absorber of radiation consists of a box that is light tight except for an aperture in one of the sides.
Any radiation which then enters the
hole is scattered and absorbed by repeated
reflections so only an infinitesimal fraction
can possibly escape. The blackness which is
obtained at the aperture
is nearly equal to a blackbody and almost perfect
for all wavelengths.
By providing such an isothermal cavity with a suitable heater
it becomes what is termed
a cavity radiator. An isothermal cavity
heated to a uniform temperature generates
blackbody radiation, the characteristics of
which are determined solely by the temperature of the cavity. Such cavity radiators
are commonly used as sources of radiation
in temperature reference standards in the laboratory
for calibrating thermo-graphic instruments.
If the temperature
of blackbody radiation increases to more
than 525 °C (977 °F), the source begins to be visible so that it appears
to the eye no longer black. This is the incipient red heat temperature of the radiator, which then becomes orange
or yellow as the temperature increases
further. In fact, the definition of the so-called color temperature of
an object is the temperature to which a blackbody
would have to be heated to have the
same appearance.
Now consider three expressions that describe
the radiation emitted from a blackbody.
Planck's law
MaxPlanck (1858-1947)
Max
Planck (1858-1947) was able to describe the spectral
distribution of the radiation from
a blackbody by means of the following formula:
X Ifr" \Wtltt/1H-tlTH
where:
WAO |
Blackbody spectral radiant emittance al wavelength A. |
c |
Velocity of light = 3 x 10* m/s |
h |
Planck's constant = 6.6 x 10'M Joule sec. |
k |
Boltzmann's constant = 1.4 x 1023Joule/K. |
T |
Absolute temperature (K) of a blackbody. |
A |
Wavelength (|jm). |
O
The factor 10'6 is used since
spectral emittance in the curves is expressed
in Watt/m2m.
If the factor is excluded, the dimension
will be Watt/m2um.
Planck's formula, when plotted graphically
for various temperatures, produces a family
of curves. Following any particular Planck
curve, the spectral emittance is zero at
A = 0, then increases rapidly to a maximum
at a wavelength Amax and after passing
it approaches zero again at very long wavelengths.
The higher the temperature, the shorter
the wavelength at which maximum occurs.
Wien's displacement
law
By differentiating Planck's formula with respect to A, and finding
the maximum, we have:
This is Wien's formula (after Wilhelm
Wien, 1 864-1 928), which expresses mathematically the common observation that colors
vary from red to orange or yellow as the temperature
of a thermal radiator increases. The wavelength
of the color is the same as the wavelength
calculated for Amax. A good approximation
of the value of Amax for a
given blackbody temperature is obtained by
applying the rule-of-thumb 3 000/T urn.
Thus, a very hot star such as Sirius (1 1
000 K), emitting bluish-white light, radiates with
the peak of spectral radiant emittance occurring
within the invisible ultraviolet spectrum,
at wavelength 0.27 urn.

WilhelmWien (1864-1928)
The sun {approx. 6 000 K) emits yellow light,
peaking at about 0.5 um in the middle of
the visible light spectrum.
At
room temperature (300 K] the peak of radiant
emittance lies at 9.7 urn, in the far infrared, while at the temperature of liquid nitrogen
(77 K) the maximum of the almost insignificant
amount of radiant emittance occurs at 38
um, in the extreme infrared wavelengths.
0 5 10 15 20 25 30
Planckian curves plotted on semi-log scales from TOOK to 1000 K. The dotted line represents
the locus of maximum radiant emittance at
each temperature as described by Wien's displacement
law. 1:
Spectral radiant emittance (W/cm2 (|jm|);
2: Wavelength ((jm).
By integrating Planck's
formula from A = 0 to A = », we obtain the total
radiant emit-tance
(Wb) of a blackbody:
Wb-aTl [Watt/m2]
This
is the Stefan-Boltzmann formula (after Josef
Stefan, 1835-1893, and Ludwig Boltzmann, 1844-1906),
which states that the total emissive power
of a blackbody is proportional
to the fourth power of its absolute temperature.
Graphically, Wb represents
the area below the Planck curve for a particular
temperature. It can be shown that the radiant emittance in the interval A = 0
to Amax is only 25 % of the total,
which represents about the amount
of the sun's radiation which lies inside
the visible light spectrum.
Josef Stefan (1835-1893), and Ludwig Boltzmann
(1844-1906)
Using the Stefan-Boltzmann formula to calculate the power radiated
by the human body,
at a temperature of 300 K and an external
surface area of approx. 2 m2,
we obtain 1 kW. This power loss could not be sustained if
it were not for the compensating absorption
of radiation from surrounding surfaces, at
room temperatures which do not vary
too drastically from the temperature of the
body-or, of course, the addition of clothing.
Non-blackbody emitters
So far, only blackbody radiators and blackbody
radiation have been discussed. However,
real objects almost never comply with these
laws over an extended wavelength region - although they may approach the blackbody
behavior in certain spectral intervals.
For example, a certain type of white paint
may appear perfectly white in the
visible light spectrum, but becomes distinctly gray at
about 2 urn, and beyond 3 um it is almost black.
There are three processes which can occur that prevent a real object
from acting like a
blackbody: a fraction of the incident radiation
a may be absorbed, a fraction p may be
reflected, and a fraction t may
be transmitted.
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