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Infrared technology over time

Less than 200 years ago the existence of the infrared portion of the electromagnetic spectrum wasn't even suspected. The original significance of the infrared spectrum, or simply 'the infrared' as it is often called, as a form of heat radiation is perhaps less obvious today than it was at the time of its discovery by Herschel in 1800.

Sir William Herschel (1738-1822)

The discovery was made accidentally during the search for a new optical material. Sir William Herschel - Royal Astronomer to King George III of England, and already famous for his discovery of the planet Uranus - was searching for an optical filter material to reduce the brightness of the sun's image in telescopes during solar observations. While testing different samples of colored glass which gave similar reductions in brightness he was intrigued to find that some of the samples passed very little of the sun's heat, while others passed so much heat that he risked eye damage after only a few seconds' observation.

Herschel was soon convinced of the necessity of setting up a systematic experiment, with the objective of finding a single material that would give the desired reduction in brightness as well as the maximum reduction in heat. He began the experiment by actually repeating Newton's prism experiment, but looking for the heating effect rather than the visual distribution of intensity in the spectrum. He first blackened the bulb of a sensitive mercury-in-gfass thermometer with ink, and with this as his radiation detector he proceeded to test the heating effect of the various colors of the spectrum formed on the top of a table by passing sunlight through a glass prism. Other ther­mometers, placed outside the sun's rays, served as controls.

As the blackened thermometer was moved slowly along the colors of the spectrum, the temperature readings showed a steady increase from the violet end to the red end. This was not entirely unexpected, since the Italian researcher, Landriani, in a similar experiment in 1777 had observed much the same effect. It was Herschel, however, who was the first to recognize that there must be a point where the heating

effect reaches a maximum, and that measurements confined to the visible portion of the spectrum failed to locate this point.

Marsillio Landriani  (1746-1815)

Moving the thermometer into the dark region beyond the red end of the spectrum, Herschel confirmed that the heating continued to increase. The maximum point, when he found it, lay well beyond the red end - in what is known today as the 'infrared wavelengths'.

When Herschel revealed his discovery, he referred to this new portion of the electro­magnetic spectrum as the 'thermometrical spectrum'. The radiation itself he sometimes referred to as 'dark heat', or simply 'the invisible rays'. Ironically, and contrary to popular opinion, it wasn't Herschel who originated the term 'infrared'. The word only began to appear in print around 75 years later, and it is still unclear who should receive credit as the originator.

Herschel's use of glass in the prism of his original experiment led to some early con­troversies with his contemporaries about the actual existence of the infrared wave­lengths. Different investigators, in attempting to confirm his work, used various types of glass indiscriminately, having different transparencies in the infrared. Through his later experiments, Herschel was aware of the limited transparency of glass to the newly-discovered thermal radiation, and he was forced to conclude that optics for the infrared would probably be doomed to the use of reflective elements exclusively (i.e. plane and curved mirrors). Fortunately, this proved to be true only until 1830, when the Italian investigator, Melloni, made his great discovery that naturally occurring rock salt (NaCI) - which was available in large enough natural crystals to be made into lenses and prisms - is remarkably transparent to the infrared. The result was that rock salt became the principal infrared optical material, and remained so for the next hundred years, until the art of synthetic crystal growing was mastered in the 1930's.

Macedonio Melloni (1798-1854)

Thermometers, as radiation detectors, remained unchallenged until 1829, the year Nobili invented the thermocouple. (Herschel's own thermometer could be read to 0.2 °C (0.036 °F), and later models were able to be read to 0.05 °C (0.09 °F)). Then a breakthrough occurred; Melloni connected a number of thermocouples in series to form the first thermopile. The new device was at least 40 times as sensitive as the best thermometer of the day for detecting heat radiation -capable of detecting the heat from a person standing three meters away.

The first so-called 'heat-picture' became possible in 1840, the result of work by Sir John Herschel, son of the discoverer of the infrared and a famous astronomer in his own right. Based upon the differential evaporation of a thin film of oil when exposed to a heat pattern focused upon it, the thermal image could be seen by reflected light where the interference effects of the oil film made the image visible to the eye. Sir John also managed to obtain a primitive record of the thermal image on paper, which he called a 'thermograph'.

Samuel P. Langley (1834-1906)

The improvement of infrared-detector sensitivity progressed slowly. Another major breakthrough, made by Langley in 1880, was the invention of the bolometer. This consisted of a thin blackened strip of platinum connected in one arm of a Wheatstone bridge circuit upon which the infrared radiation was focused and to which a sensitive galvanometer responded. This instrument is said to have been able to detect the heat from a cow at a distance of 400 meters.

An English scientist, Sir James Dewar, first introduced the use of liquefied gases as cooling agents (such as liquid nitrogen with a temperature of -196 °C (-320.8 °F)) in low temperature research. In 1892 he invented a unique vacuum insulating container in which it is possible to store liquefied gases for entire days. The common 'thermos bottle', used for storing hot and cold drinks, is based upon his invention.

Between the years 1900 and 1920, the inventors of the world 'discovered' the infrared. Many patents were issued for devices to detect personnel, artillery, aircraft, ships -and even icebergs. The first operating systems, in the modern sense, began to be developed during the 1914-18 war, when both sides had research programs devoted to the military exploitation of the infrared. These programs included experimental systems for enemy intrusion/detection, remote temperature sensing, secure commu­nications, and 'flying torpedo' guidance. An infrared search system tested during this period was able to detect an approaching airplane at a distance of 1.5 km (0.94 miles), or a person more than 300 meters (984 ft.) away.

The most sensitive systems up to this time were all based upon variations of the bolometer idea, but the period between the two wars saw the development of two revolutionary new infrared detectors: the image converter and the photon detector. At first, the image converter received the greatest attention by the military, because it enabled an observer for the first time in history to literally 'see in the dark'. However, the sensitivity of the image converter was limited to the near infrared wavelengths, and the most interesting military targets (i.e. enemy soldiers) had to be illuminated by infrared search beams. Since this involved the risk of giving away the observer's position to a similarly-equipped enemy observer, it is understandable that military interest in the image converter eventually faded.

The tactical military disadvantages of so-called 'active' (i.e. search beam-equipped) thermal imaging systems provided impetus following the 1939-45 war for extensive secret military infrared-research programs into the possibilities of developing 'passive' (no search beam) systems around the extremely sensitive photon detector. During this period, military secrecy regulations completely prevented disclosure of the status of infrared-imaging technology. This secrecy only began to be lifted in the middle of the 1950's, and from that time adequate thermal-imaging devices finally began to be available to civilian science and industry.

middle infrared (3-6 |jm), the far infrared (6-15 um) and the extreme infrared (15-100 um). Although the wavelengths are given in |jm (micrometers), other units are often still used to measure wavelength in this spectral region, e.g. nanometer (nm) and Angstrom (A).

The relationships between the different wavelength measurements is:

10,000 A = 1000nm = 1u =1um

Blackbody radiation

A blackbody is defined as an object which absorbs all radiation that impinges on it at any wavelength. The apparent misnomer black relating to an object emitting radi­ation is explained by Kirchhoff's Law (after GustavRobertKirchhoff,

1824-1887), which states that a body capable of absorbing all radiation at any wavelength is equally capable in the emission of radiation.

 

Gustav Robert Kirchhoff (1824-1887)

The construction of a blackbody source is, in principle, very simple. The radiation characteristics of an aperture in an isotherm cavity made of an opaque absorbing material represents almost exactly the properties of a blackbody. A practical applica­tion of the principle to the construction of a perfect absorber of radiation consists of a box that is light tight except for an aperture in one of the sides. Any radiation which then enters the hole is scattered and absorbed by repeated reflections so only an in­finitesimal fraction can possibly escape. The blackness which is obtained at the aperture is nearly equal to a blackbody and almost perfect for all wavelengths.

By providing such an isothermal cavity with a suitable heater it becomes what is termed a cavity radiator. An isothermal cavity heated to a uniform temperature gen­erates blackbody radiation, the characteristics of which are determined solely by the temperature of the cavity. Such cavity radiators are commonly used as sources of ra­diation in temperature reference standards in the laboratory for calibrating thermo-graphic instruments.

If the temperature of blackbody radiation increases to more than 525 °C (977 °F), the source begins to be visible so that it appears to the eye no longer black. This is the incipient red heat temperature of the radiator, which then becomes orange or yellow as the temperature increases further. In fact, the definition of the so-called color temperature of an object is the temperature to which a blackbody would have to be heated to have the same appearance.

Now consider three expressions that describe the radiation emitted from a blackbody.

Planck's law

MaxPlanck (1858-1947)

Max Planck (1858-1947) was able to describe the spectral distribution of the radiation from a blackbody by means of the following formula:

X Ifr" \Wtltt/1H-tlTH

where:




WAO

Blackbody spectral radiant emittance al wavelength A.

c

Velocity of light = 3 x 10* m/s

h

Planck's constant = 6.6 x 10'M Joule sec.

k

Boltzmann's constant = 1.4 x 1023Joule/K.

T

Absolute temperature (K) of a blackbody.

A

Wavelength (|jm).

O The factor 10'6 is used since spectral emittance in the curves is expressed in Watt/m2m. If the factor is excluded, the dimension will be Watt/m2um.


Planck's formula, when plotted graphically for various temperatures, produces a family of curves. Following any particular Planck curve, the spectral emittance is zero at A = 0, then increases rapidly to a maximum at a wavelength Amax and after passing it approaches zero again at very long wavelengths. The higher the temperature, the shorter the wavelength at which maximum occurs.

 Wien's displacement law

 By differentiating Planck's formula with respect to A, and finding the maximum, we have:


2898 ——

, [/

This is Wien's formula (after Wilhelm Wien, 1 864-1 928), which expresses mathemati­cally the common observation that colors vary from red to orange or yellow as the temperature of a thermal radiator increases. The wavelength of the color is the same as the wavelength calculated for Amax. A good approximation of the value of Amax for a given blackbody temperature is obtained by applying the rule-of-thumb 3 000/T urn. Thus, a very hot star such as Sirius (1 1 000 K), emitting bluish-white light, radiates with the peak of spectral radiant emittance occurring within the invisible ultraviolet spectrum, at wavelength 0.27 urn.



WilhelmWien (1864-1928)

The sun {approx. 6 000 K) emits yellow light, peaking at about 0.5 um in the middle of the visible light spectrum.

At room temperature (300 K] the peak of radiant emittance lies at 9.7 urn, in the far infrared, while at the temperature of liquid nitrogen (77 K) the maximum of the almost insignificant amount of radiant emittance occurs at 38 um, in the extreme infrared wavelengths.



m




10J-

10'-

10"



0        5          10        15         20        25        30

Planckian curves plotted on semi-log scales from TOOK to 1000 K. The dotted line represents the locus of maximum radiant emittance at each temperature as described by Wien's displacement law. 1: Spectral radiant emittance (W/cm2 (|jm|); 2: Wavelength ((jm).

Stefan-Boltzmann's law


By integrating Planck's formula from A = 0 to A = », we obtain the total radiant emit-tance (Wb) of a blackbody:

Wb-aTl [Watt/m2]

This is the Stefan-Boltzmann formula (after Josef Stefan, 1835-1893, and Ludwig Boltzmann, 1844-1906), which states that the total emissive power of a blackbody is proportional to the fourth power of its absolute temperature. Graphically, Wb repre­sents the area below the Planck curve for a particular temperature. It can be shown that the radiant emittance in the interval A = 0 to Amax is only 25 % of the total, which represents about the amount of the sun's radiation which lies inside the visible light spectrum.



Josef Stefan (1835-1893), and Ludwig Boltzmann (1844-1906)

Using the Stefan-Boltzmann formula to calculate the power radiated by the human body, at a temperature of 300 K and an external surface area of approx. 2 m2, we obtain 1 kW. This power loss could not be sustained if it were not for the compensating ab­sorption of radiation from surrounding surfaces, at room temperatures which do not vary too drastically from the temperature of the body-or, of course, the addition of clothing.

Non-blackbody emitters

So far, only blackbody radiators and blackbody radiation have been discussed. How­ever, real objects almost never comply with these laws over an extended wavelength region - although they may approach the blackbody behavior in certain spectral in­tervals. For example, a certain type of white paint may appear perfectly white in the visible light spectrum, but becomes distinctly gray at about 2 urn, and beyond 3 um it is almost black.

There are three processes which can occur that prevent a real object from acting like a blackbody: a fraction of the incident radiation a may be absorbed, a fraction p may be reflected, and a fraction t may be transmitted.

 

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